Among the exhibits are works by I. Aivazovsky, A. and Alb. Benoit, M. Dobuzhinsky, A. Ivanov, P. Konchalovsky, B. Kustodiev, V. Lebedev, M. Nesterov, K. Petrov-Vodkin, Z. Serebryakova, I. Shishkin. A special place in the collection of the Rzhevskys is occupied by furniture, floor and mantel clocks of Western Europe and Russia of the 18th-19th centuries. Many of these items have no analogues in domestic museum collections.
A unique collection of the Rzhevsky brothers, including works of painting, graphics, sculpture and decorative art, has been formed for more than half a century. In total, it consists of 503 works, half of which are paintings and graphics of the second half of the XIX - early XX centuries.